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      Raw data for new compounds described in the paper: "Remote Nucleophilic Allylation by Allylrhodium Chain Walking"

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      Raw data.zip (1.024Gb)
      Publication date
      2018-07-23
      Creators
      Lam, Hon Wai
      Metadata
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      Description
      Raw data for new compounds described in the paper: "Remote Nucleophilic Allylation by Allylrhodium Chain Walking". Metal migration through a carbon chain is a versatile method for achieving remote functionalization. However, almost all known examples involve the overall net migration of alkylmetal species. Here, we report that allylrhodium species obtained from hydrorhodation of 1,3-dienes undergo chain walking toward esters, amides, or (hetero)arenes over distances of up to eight ethylene units. The final, more highly conjugated allylrhodium species undergo nucleophilic allylation with aldehydes and an imine to give Z-homoallylic alcohols and amines, respectively.
      External URI
      • https://rdmc.nottingham.ac.uk/handle/internal/369
      DOI
      • http://doi.org/10.17639/nott.365
      Related publication DOI
      • 10.1002/chem.201803574
      Subjects
      • Homogeneous catalysis
      • Isomerization
      • Rhodium
      • allylation; chain walking; homogeneous catalysis; isomerization; rhodium
      • Physical sciences::Chemistry::Physical chemistry
      • Q Science::QD Chemistry::QD450 Physical and theoretical chemistry
      Divisions
      • University of Nottingham, UK Campus::Faculty of Science::School of Chemistry
      Deposit date
      2018-07-23
      Data type
      IR, NMR, and mass spectrometry data
      Contributors
      • Groves, Alistair
      • Martínez, Jose
      • Smith, Joshua
      Funders
      • Engineering & Physical Sciences Research Council
      • Other
      • The Basque Country Government
      • Leverhulme Trust
      • GlaxoSmithKline
      Grant number
      • EP/M50810X/1 and EP/K504348/1 and RPG-2016-341
      Data collection method
      Using IR, NMR, and mass spectrometers
      Resource languages
      • en
      Publisher
      The University of Nottingham

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