Browsing by Author "Walker, Gavin"

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Synthesis of the bulky phosphanide [P(SiiPr3)2]− and its stabilisation of low-coordinate Group 12 complexes

Churchill, Olivia; Dase, Antonia; Taylor, Laurence; Argent, Stephen; Kays, Deborah (University of Nottingham, 2025-01-25)

Here, we report the first practical synthesis of the bulky phosphanide anion [P(SiiPr3)2]− in synthetically useful yields, and its complexation to Group 12 metals. The ligand is obtained as the sodium salt NaP(SiiPr3)2 1 ...